Interpenetration as a Mechanism for Liquid-Liquid Phase Transitions

We study simple lattice systems to demonstrate the influence of interpenetrating bond networks on phase behavior. We promote interpenetration by using a Hamiltonian with a weakly repulsive interaction with nearest neighbors and an attractive interaction with second-nearest neighbors. In this way, bond networks will form between second-nearest neighbors, allowing for two (locally) distinct networks to form. We obtain the phase behavior from analytic solution in the mean-field approximation and exact solution on the Bethe lattice. We compare these results with exact numerical results for the phase behavior from grand canonical Monte Carlo simulations on square, cubic, and tetrahedral lattices. All results show that these simple systems exhibit rich phase diagrams with two fluid-fluid critical points and three thermodynamically distinct phases. We also consider including third-nearest-neighbor interactions, which give rise to a phase diagram with four critical points and five thermodynamically distinct phases. Thus the interpenetration mechanism provides a simple route to generate multiple liquid phases in single-component systems, such as hypothesized in water and observed in several model and experimental systems. Additionally, interpenetration of many such networks appears plausible in a recently considered material made from nanoparticles functionalized by single strands of DNA.Comment: 12 pages, 9 figures, submitted to Phys. Rev.

Transmission efficiency limit for nonlocal metalenses

The rapidly advancing capabilities in nanophotonic design are enabling complex functionalities limited mainly by physical bounds. The efficiency of transmission is a major consideration, but its ultimate limit remains unknown for most systems. Here, we introduce a matrix formalism that puts a fundamental bound on the channel-averaged transmission efficiency of any passive multi-channel optical system based only on energy conservation and the desired functionality, independent of the interior structure and material composition. Applying this formalism to diffraction-limited nonlocal metalenses with a wide field of view, we show that the transmission efficiency must decrease with the numerical aperture for the commonly adopted designs with equal entrance and output aperture diameters. We also show that reducing the size of the entrance aperture can raise the efficiency bound. This work reveals a fundamental limit on the transmission efficiency as well as providing guidance for the design of high-efficiency multi-channel optical systems

Optimization of sharp and viewing-angle-independent structural color

Structural coloration produces some of the most brilliant colors in nature and has many applications. However, the two competing properties of narrow bandwidth and broad viewing angle have not been achieved simultaneously in previous studies. Here, we use numerical optimization to discover geometries where a sharp 7% bandwidth in scattering is achieved, yet the peak wavelength varies less than 1%, and the peak height and peak width vary less than 6% over broad viewing angles (0--90$^\circ$) under a directional illumination. Our model system consists of dipole scatterers arranged into several rings; interference among the scattered waves is optimized to yield the wavelength-selective and angle-insensitive response. Such designs can be useful for the recently proposed transparent displays that are based on wavelength-selective scattering